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Faculty of Biology, Chemistry & Earth Sciences

Macromolecular Chemistry II – Prof. Dr. Andreas Greiner (Macromolecular Chemistry & Technology) & Prof. Dr. Seema Agarwal (Advanced Sustainable Polymers)

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Poly(p-xylylene)s: synthesis, polymer analogeous reactions, and perspectives on structure-property relationships.
A. Greiner, S. Mang, O. Schäfer, P. Simon, Acta Polym. 1997, 48, 1-15. DOI: 10.1002/actp.1997.010480101

Poly(1,4-xylylene)s: polymer films by chemical vapour deposition.
A. Greiner, Trends in Polymer Science 1997, 5, 12-16.

Poly(p-xylylene)s (structure, properties, and applications).
A. Greiner, The Polymeric Materials Encyclopedia 1996, 9, 7171-7180, Ed. J. C. Salamone, CRC Press, Bocca Raton.

Original papers

Hierarchically structured poly(alkyl-p-xylylene) nonwovens with superhydrophobic properties. 
I. Paulus, T. Moss, A. Greiner, Macromol. Mater. Eng. 2016, 301, 1225-1231. DOI: 10.1002/mame.201600140

Chemical vapour deposition of soluble poly(p-xylylene) copolymers with tuneable properties. 
I. E. Paulus, M. Heiny, V. P. Shastri, A. Greiner, Polym. Chem. 2016, 7, 54-62. DOI: 10.1039/c5py01343g

Highways for ions in polymers-3D-imaging of electrochemical interphase formation.
V. Wesp, J. Zakel, M. Schaefer, I. Paulus, A. Greiner, K. M. Weitzel, Electrochimica Acta 2015, 170, 122-130. DOI: 10.1016/j.electacta.2015.04.117

Bombardment induced ion transport – part III: experimental potassium ion conductivities in poly(para-xylylene).
S. Schulze, M. Schäfer,  A. Greiner, K.-M. Weitzel, Phys. Chem. Chem. Phys. 2013, 15, 1481-1487. DOI:10.1039/c2cp43144k

Synthesis, properties, and processing of new siloxane-substituted poly(p-xylylene) via CVD.
A. K. Bier, M. Bognitzki, A. Schmidt, A. Greiner, E. Gallo, P. Klack, B. Schartel, Macromolecules, 2012, 45, 633-639. DOI: 10.1021/ma2021369

Synthesis, structure, and properties of alkyl substituted PPXs by chemical vapor deposition for stent coatings.
A. K. Bier, M. Bognitzki, J. Mogk, A. Greiner, Macromolecules, 2012, 45, 1151-1157. DOI: 10.1021/ma202270w

Thermally cross-linkable poly(p-xylylene)s for advanced low-dielectric applications.
S. V. Mulpuri, B.-G. Shin, M. Bognitzki, A. Greiner, D. Y. Yoon, Macromol. Chem. Phys. 2012, 213, 705-712. DOI: 10.1002/macp.201100558

In vitro study of dexamethasone release from poly(p-xylylene) films.
P. Hanefeld, S. Agarwal, R. Kumar, A. Greiner, Macromol. Chem. Phys. 2010, 211, 265-269. DOI: 10.1002/macp.200900537

Investigation of the ion permeability of poly(p-xylylene) films.
P. Hanefeld, F. Sittner, W. Ensinger, A. Greiner, e-Polymers 2006, No. 26.

Synthesis and characterisation of graft co-polymers of derivatives of poly(p-xylylene).
R. Madan, A. Greiner, Designed Monomers and Polymers 2006, 9, 81-87. DOI: 10.1163/156855506775526214

Synthesis and properties of novel poly(p-xylylene)s with aliphatic substituents.
M. Ishaque, S. Agarwal, A. Greiner, e-Polymers 2002, No. 31.

Efficient control on molecular weight in the synthesis of poly(p-xylylene)s via Gilch polymerization.
F. Brink-Spalink, A. Greiner, Macromolecules 2002, 35, 3315-3317. DOI: 10.1021/ma010623c

Synthesis and structure-property relationships of novel poly(p-xylylene)s with aromatic substituents.
M. Ishaque, R. Wombacher, J. H. Wendorff, A. Greiner, e-Polymers 2001, No. 5.

Synthesis and properties of omega-phenylalkyl-substituted poly(p-xylylene)s prepared by base induced 1,6-dehydrohalogenation.
O. Schäfer, F. Brink-Spalink, B. Smarsly, C. Schmidt, J. H. Wendorff, C. Witt, T. 
Kissel, A. Greiner, Macromol. Chem. Phys. 1999, 200, 1942-1949. DOI: 10.1002/(SICI)1521-3935(19990801)200:8<1942::AID-MACP1942>3.0.CO;2-H

Synthesis of poly(p-xylylene)s by base induced 1.6-dehydrohalogenation - control of the degree of polymerization.
O. Schäfer, F. Brink-Spalink, A. Greiner, Macromol. Rapid Commun. 1999, 20, 190-193. DOI: 10.1002/(SICI)1521-3927(19990401)20:4<190::AID-MARC190>3.0.CO;2-Z

Control of crystalline modifications of poly(p-xylylene) by copolymerization.
B. Smarsly, F. Brink-Spalink, O. Schäfer, C. Schmidt, A. Greiner, W. Ruland, J. H. Wendorff, Macromol. Chem. Phys. 1999, 200, 714-718. DOI: 10.1002/(SICI)1521-3935(19990401)200:4<714::AID-MACP714>3.0.CO;2-6

Synthesis of OH-functionalized poly(p-xylylene)s by reductive coupling polymerization of aromatic dialdehydes with catalytic amounts of divalent Samarium compounds.
N. E. Brandukova-Szmikowski, A. Greiner, Acta Polym. 1999, 50, 141-144. DOI: 10.1002/(SICI)1521-4044(19990401)50:4<141::AID-APOL141>3.0.CO;2-T

Synthesis of OH-functionalized poly(p-xylylene)s by reductive coupling polymerization of aromatic dialdehydes with stoichiometric amounts of divalent Samarium compounds.
N. E. Brandukova-Szmikowski, S. Agarwal, A. Greiner, Acta Polym. 1999, 50, 35-39. DOI: 10.1002/(SICI)1521-4044(19990101)50:1<35::AID-APOL35>3.0.CO;2-H

Poly(p-xylylene) and its derivatives by chemical vapor deposition: synthesis, 
mechanism, and structure.
P. Simon, S. Mang, A. Hasenhindl, W. Gronski, A. Greiner, Macromolecules 1998, 31, 8775-8780. DOI: 10.1021/ma9808070

Structural analysis of PPX prepared by vapor phase pyrolysis of [2.2]paracyclophane.
C. Schmidt, V. Stümpflen, J. H. Wendorff, A. Hasenhindl, W. Gronski, M. Ishaque, A.
Greiner, Acta Polym. 1998, 49, 232-235. DOI: 10.1002/(SICI)1521-4044(199805)49:5<232::AID-APOL232>3.0.CO;2-L

Soluble and amorphous, phenyl substituted poly(1,4-xylylene) by chemical vapor deposition.
O. Schäfer, A. Greiner, Macromolecules 1996, 29, 6074-6075. DOI: 10.1021/ma960681b

Samarium (II) iodine: A diastereoselective reagent for the synthesis of aromatic 1,2-diol structures - model reactions.
V. U. Wege, A. Greiner, Acta Polym. 1995, 46, 396-403. DOI: 10.1002/actp.1995.010460508

New synthetic approach to OH-functionalized poly(p-xylylene)s by coupling of 
aromatic dialdehydes and diketones in the presence of SmI2.
V. U. Wege, A. Greiner, Acta Polym. 1995, 46, 391-395. DOI: 10.1002/actp.1995.010460507

New synthetic approach to film forming poly-p-xylylene by gas phase pyrolysis of esters derivated from a, α'-dihydroxy-p-xylylene.
P. Simon, A. Greiner, Polym. J.  1992, 24, 1317-1320. DOI: 10.1295/polymj.24.1317

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