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Faculty of Biology, Chemistry & Earth Sciences

Macromolecular Chemistry II – Prof. Dr. Andreas Greiner & Prof. Dr. Seema Agarwal

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Polarized blue photoluminescence of mesoscopically ordered electrospun non-conjugated polyacrylonitrile nanofibers

02.04.2020

Xiaojian Liao, Frank-Julian Kahle, Bin Liu, Heinz Bässler, Xinghong Zhang, Anna Köhler, Andreas Greiner

Mater. Horiz., 2020, Advance Article https://doi.org/10.1039/D0MH00002G

Conjugated polymers and oligomers that emit polarized light are used as active materials in various optoelectronic device applications, notably organic light-emitting diodes (OLEDs). Here, we demonstrate the fabrication of electrospun polarized light-emitting fibers from a non-conjugated polymer that can be aligned by a simple heat-stretching process. Upon excitation at 340 nm, ribbons made from the nanofibers show polarized deep blue luminescence with an anisotropy of 0.37 and a quantum yield of about 31%. Furthermore, they exhibit room temperature green phosphorescence with a lifetime of about 200 ms as well as a delayed deep blue fluorescence resulting from triplet–triplet annihilation (non-coherent photon upconversion) (TTA). Wide and small angle X-ray scattering experiments show that the stretched electrospun fibers are highly aligned with nearly perfect uniaxial orientation within the fabricated ribbons. This results in a mechanically robust and flexible material, with a high specific tensile strength (534 ± 28) MPa cm3 g−1 and toughness (79 ± 7) J g−1. The combination of efficient polarized deep blue luminescence, room temperature phosphorescence, TTA, mechanical robustness and flexibility of these fibers opens up new avenues for applications of non-conjugated polymers.

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